Math problem set Grade 12 Science
Kingsley Cove Brackish RO: Recovery and Mass Balance
A grade 12 problem set on a fictional reverse-osmosis plant, finding recovery, salt rejection, a brine mass balance, concentration factor, and daily treatment energy.
Objectives
- Students will calculate recovery, brine flow, and salt rejection for a reverse-osmosis plant.
- Students will use a salt mass balance to find the brine concentration.
- Students will compute daily treatment energy and compare it with conventional treatment.
Vocabulary
- Reverse osmosis
- Reverse osmosis cleans water by pushing it through a membrane with holes so tiny that salt and most other dissolved things cannot fit through. It can even turn seawater into fresh water.
Also: recovery, salt rejection, concentration factor, mass balance
Teacher overview
The fictional Kingsley Cove plant pushes brackish groundwater through reverse-osmosis membranes, splitting the feed into clean permeate and a saltier brine. This set has students find the recovery and salt rejection, then use a mass balance to show where the rejected salt goes and how energy-hungry the process is. A common misconception is that the salt removed from the permeate simply disappears; the mass balance in problems 4 through 7 makes clear that every pound of salt not in the permeate leaves in the smaller brine stream, which raises the brine concentration well above the feed.
Problems
Suppose the town of Kingsley Cove runs its brackish reverse-osmosis plant at a feed flow of 4.0 MGD, producing a permeate flow of 2.6 MGD. The feed water carries 3,200 mg/L of total dissolved solids, and the permeate carries 90 mg/L. Use the pounds formula, load (lbs/day) = concentration (mg/L) x flow (MGD) x 8.34.
Find the plant's recovery, where recovery = permeate flow / feed flow, as a percentage.
Find the brine (concentrate) flow in MGD.
Find the salt rejection, where rejection = (1 - permeate TDS / feed TDS) x 100. Round to the nearest hundredth.
Find the salt load entering in the feed, in pounds per day.
Find the salt load leaving in the permeate, in pounds per day.
Use a mass balance to find the salt load leaving in the brine, then find the brine TDS in mg/L. (Brine TDS = brine salt load / (brine flow x 8.34).)
Find the concentration factor two ways: as brine TDS divided by feed TDS, and as 1 / (1 - recovery). Compare the two values.
In our scenario the plant uses 3.5 kWh of energy per 1,000 gallons of permeate, while conventional treatment uses about 1 to 2 kWh per 1,000 gallons. Find the plant's daily energy for its permeate, then state how many times the upper conventional figure of 2 kWh that per-thousand-gallon rate represents.
From Water for Schools (waterforschools.org). This material is in the public domain (CC0) and may be copied, edited, and shared freely.
Answer Key
Answer: 65%.
Recovery = 2.6 MGD / 4.0 MGD = 0.65, or 65 percent.Answer: 1.4 MGD.
Brine flow = feed - permeate = 4.0 - 2.6 = 1.4 MGD.Answer: 97.19%.
Rejection = (1 - 90 / 3,200) x 100 = (1 - 0.028125) x 100 = 97.19 percent.Answer: 106,752 lbs/day.
Feed salt load = 3,200 mg/L x 4.0 MGD x 8.34 = 106,752 pounds per day.Answer: 1,951.56 lbs/day.
Permeate salt load = 90 mg/L x 2.6 MGD x 8.34 = 1,951.56 pounds per day.Answer: 8,976 mg/L.
Brine salt load = 106,752 - 1,951.56 = 104,800.44 pounds per day. Brine TDS = 104,800.44 / (1.4 x 8.34) = 104,800.44 / 11.676 = 8,976 mg/L.Answer: about 2.8 versus 2.86.
Brine TDS / feed TDS = 8,976 / 3,200 = 2.81. The ideal factor 1 / (1 - 0.65) = 1 / 0.35 = 2.86. The measured factor is slightly lower because a small amount of salt leaves in the permeate rather than concentrating entirely in the brine.Answer: 9,100 kWh/day, which is 1.75 times the 2 kWh rate.
Permeate is 2.6 MGD = 2,600,000 gallons per day, or 2,600 thousand-gallon units. Energy = 2,600 x 3.5 = 9,100 kWh per day. The 3.5 kWh rate is 3.5 / 2 = 1.75 times the upper conventional figure of 2 kWh per 1,000 gallons.
Differentiation
Support
Provide the pounds formula on a card and pre-label the feed, permeate, and brine streams on a flow diagram so students can see which flow and concentration each problem needs.
Extension
Ask students to find the recovery that would raise the brine TDS to about 12,000 mg/L, assuming the feed TDS and near-complete salt rejection hold, and explain why higher recovery makes the brine harder to dispose of.
ELL supports
Provide a labeled flow diagram with the words "feed," "permeate," and "brine" beside their arrows, and a sentence frame for problem 7 comparing "measured" and "ideal" concentration factors.
Extensions
Have students look up the reported recovery of a real seawater or brackish desalination plant, compare it with the 65 percent here, and explain why seawater plants often run at lower recovery than brackish plants.